As an administrator, you will see the Export button next to the settings of the Org Chart. You may click on the person you want to export data from, and then click the Export button. A drawer opens that allows you to export the data with a few options:
Include only direct reports or all reports
Exclude contractors
Click the Export button within the drawer, and download a CSV file with the people matching the criteria to your default download directory on your local machine. The file will include the following fields: